Metal naphthenates are salts of these naphthenic acids1 having the formula M(Naphthenate)2.2 They can be found naturally from the combination of naphthenic acids in crude oil with metal ions contained in water.
These naphthenate salts are soluble in certain organic carrier liquids and are an effective source of metal ions in organic media. Traditional applications2 include use in paint drying, wood treatment, anti-fouling agents, detergents, insecticides, fungicides, wetting agents, lubricants, surfactants, and corrosion inhibitors.
Listed below are various metal naphthenates that Strem has available for purchase in the UK, we have many in stock, so phone us for advice
Item Number |
Metal |
% Metal Content |
Carrier Liquid |
93-2027 |
Calcium |
4 |
35% in mineral spirits |
24-2427 |
Chromium |
2-2.5 |
30-40% in heavy naphtha |
93-2424 |
Chromium |
2 |
30% in mineral spirits |
93-2710 |
Cobalt |
6 |
53% in mineral spirits |
29-6750 |
Copper |
8 |
77% in mineral spirits |
93-2613 |
Iron |
6 |
40% in mineral spirits |
26-2600 |
Iron |
12 |
80% in mineral spirits |
93-1236 |
Magnesium |
3.5-8.0 |
|
93-2516 |
Manganese |
6 |
56% in mineral spirits |
93-2829 |
Nickel |
6-8 |
60% in toluene |
93-6206 |
Samarium |
8-10 |
|
23-4400 |
Vanadium |
2.8-3.2 |
35% in naphthenic acid |
93-3908 |
Yttrium |
7-13 |
60% in toluene |
93-3037 |
Zinc |
10 |
65% in mineral spirits |
These compounds are also related to a source of metal soaps: metal 2-ethyhexanoates
References:
- Kirk‐Othmer Encyclopedia of chemical technology, 2000 (https://onlinelibrary.wiley.com/doi/full/10.1002/0471238961.1401160802180905.a01)
- For example see; Performance of copper naphthenate and its analogues as ground contact wood preservatives, Bioresource Technology, 2005, 96(10), 1135.
Image: Example of cyclopentyl and cyclohexyl mixture comprising
Metal Naphthenate (n = 0-5 variable number of carbons).
(For different metals available see table)